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3-Aminocrotononitrile, (E)+(Z), 96%

Product Code. 11327395
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Product Code. 11327395 Supplier Thermo Scientific Alfa Aesar Supplier No. L05316.22
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Descripción

CAS: 1118-61-2 | C4H6N2 | 82.11 g/mol

3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ?-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ɑ-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.

Solubility
Very soluble in water, soluble in ethanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.
TRUSTED_SUSTAINABILITY

Identificadores de productos químicos

CAS 1118-61-2
Molecular Formula C4H6N2
Molecular Weight (g/mol) 82.11
MDL Number MFCD00008071,MFCD00008071
InChI Key DELJOESCKJGFML-DUXPYHPUSA-N
Synonym 3-aminocrotononitrile, 2z-3-aminobut-2-enenitrile, 3-amino-2-butenenitrile, z-3-aminobut-2-enenitrile, beta-aminocrotononitrile, 3-amino-2-butenonitrile, 2-amino-1-propenecarbonitrile, 3-amino-crotononitrile, beta-amino-crotononitrile, 2z-3-amino-2-butenenitrile
PubChem CID 5325263
IUPAC Name (Z)-3-aminobut-2-enenitrile
SMILES C\C(N)=C/C#N

Especificaciones

Melting Point ∼70°C to 75°C
Boiling Point 120°C (4 mmHg)
Flash Point 154°C (309°F)
Quantity 100 g
Beilstein 1719815
Solubility Information Very soluble in water,soluble in ethanol.
Formula Weight 82.11
Percent Purity 96%
Chemical Name or Material 3-Aminocrotononitrile, (E)+(Z)

RUO – Research Use Only

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