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  7. cis-Cyclooctene, 95%, stab.

cis-Cyclooctene, 95%, stab.

Product Code. 11445553
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Product Code. 11445553 Supplier Thermo Scientific Alfa Aesar Supplier No. A13477.AE
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Description

CAS: 931-87-3 | C8H14 | 110.20 g/mol

cis-Cyclooctene is used as a displaced ligand in chlorobis(cyclooctene)rhodium dimer and chlorobis(cyclooctene)iridium dimer in organometallic chemistry. It acts as a monomer used in synthetic chemistry. It is used to prepare 1-chloro-4-(trichloromethyl) cyclooctane by reaction with carbon tetrachloride using dichlorotris(triphenylphosphine) ruthenium(II) as a catalyst. Further, it is used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
cis-Cyclooctene is used as a displaced ligand in chlorobis(cyclooctene)rhodium dimer and chlorobis(cyclooctene)iridium dimer in organometallic chemistry. It acts as a monomer used in synthetic chemistry. It is used to prepare 1-chloro-4-(trichloromethyl) cyclooctane by reaction with carbon tetrachloride using dichlorotris(triphenylphosphine) ruthenium(II) as a catalyst. Further, it is used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

Solubility
Miscible with alcohol and ether. Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 931-87-3
Molecular Formula C8H14
Molecular Weight (g/mol) 110.20
MDL Number MFCD00001753
InChI Key URYYVOIYTNXXBN-UPHRSURJSA-N
Synonym cis-cyclooctene, z-cyclooctene, cyclooctene, z, cyclooctene, 1z, cyclooct-1-ene, e-cyclooctene, 1-cyclooctene #, 1z-cyclooctene, 7z-cyclooctene, ar,e-cyclooctene
PubChem CID 638079
SMILES C1CCC\C=C/CC1

Specifications

Melting Point -16°C
Density 0.848
Boiling Point 145°C to 146°C
Flash Point 25°C (77°F)
Odor Recognizable
Refractive Index 1.47
Quantity 100 mL
UN Number UN3295
Beilstein 1280166
Sensitivity Air Sensitive
Solubility Information Miscible with alcohol and ether. Immiscible with water.
IUPAC Name cyclooctene
Formula Weight 110.2
Percent Purity 95%
Chemical Name or Material cis-Cyclooctene, stabilized
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Safety and Handling

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Product Identifier
  • cis-Cyclooctene
 Signal Word
  • Danger
 Hazard Category
  • LONG-TERM AQUATIC HAZARD Chronic 1
  • Aspiration toxicity Category 1
  • Flammable liquid Category 3
 Hazard Statement
  • H226-Flammable liquid and vapour.
  • H304-May be fatal if swallowed and enters airways.
  • H410-Very toxic to aquatic life with long lasting effects.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P273-Avoid release to the environment.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P331-Do NOT induce vomiting.
  • P403+P233-Store in a well-ventilated place. Keep container tightly closed.
 Supplemental information
  • MIXTURE LIST-Contains : (Z)-Cyclooctene
SDS

RUO – Research Use Only

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