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Diethyl diallylmalonate, 97+%

Product Code. 11469693
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Product Code. 11469693 Supplier Thermo Scientific Alfa Aesar Supplier No. A12460.09
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Description

CAS: 3195-24-2 | C13H20O4 | 240.299 g/mol

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 3195-24-2
Molecular Formula C13H20O4
Molecular Weight (g/mol) 240.299
MDL Number MFCD00009126
InChI Key LYUUVYQGUMRKOV-UHFFFAOYSA-N
PubChem CID 76664
IUPAC Name diethyl 2,2-bis(prop-2-enyl)propanedioate
SMILES CCOC(=O)C(CC=C)(CC=C)C(=O)OCC

Specifications

Density 0.993
Boiling Point 242°C to 244°C
Flash Point >110°C (230°F)
Refractive Index 1.446
Quantity 10 g
Beilstein 1790529
Synonym diethyl diallylmalonate, diethyl 2,2-diallylmalonate, diallylmalonic acid diethyl ester, propanedioic acid, di-2-propenyl-, diethyl ester, 1,3-diethyl 2,2-bis prop-2-en-1-yl propanedioate, diethyl 2,2-diprop-2-enylpropane-1,3-dioate, diethyldiallylmalonate, malonic acid, diallyl-, diethyl ester, diethyl2,2-diallylmalonate, acmc-1cp69
Solubility Information Sparingly Soluble in water. (0.72g/L) (25°C)
Formula Weight 240.3
Percent Purity 98%
Chemical Name or Material Diethyl diallylmalonate
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Produktbeteckning
  • Diethyl diallylmalonate
 Signalord
  • Warning
 Riskkategorier
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Faroangivelser
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Skyddsangivelse
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
  • P332+P313-If skin irritation occurs: Get medical advice/attention.
  • P337+P313-If eye irritation persists: Get medical advice/attention.
 Kompletterande information
  • MIXTURE LIST-Contain: Diethyl diallylmalonate
SDS

RUO – Research Use Only

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