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Diisobutylaluminum hydride, 1M solution in toluene

Product Code. 15460837
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100 mL
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Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.
Product Code. 15460837 Supplier Thermo Scientific Alfa Aesar Supplier No. L14718.AE
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This item is not returnable. View return policy
Regulatory: This product is an isolated intermediate transported in accordance with Regulation (EC) 1907/2006 (REACH). All customers must complete a declaration before delivery.

Description

CAS: 1191-15-7 | C8H19Al

Diisobutylaluminum hydride reduces chiral ?-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes. I t is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-Debenzylation and ring opening of perbenzylated furanosides and convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diisobutylaluminum hydride reduces chiral ɑ-silyloxy esters to the corresponding enantiomerically-pure hydroxy aldehydes. I t is used in Pd-catalyzed reductive debromination of secondary alkyl bromides, O-Debenzylation and ring open
TRUSTED_SUSTAINABILITY

Especificaciones

CAS 1191-15-7
Density 0.805
Boiling Point ∼110°C
Flash Point 4°C (40°F)
Molecular Formula C8H19Al
Linear Formula [(CH3)2CHCH2]2AlH
MDL Number MFCD00008928
Quantity 100 mL
UN Number UN3399
Beilstein 4123663
Sensitivity Moisture sensitive
Synonym DIBAH; DIBAL-H
Solubility Information Reacts with water.
Formula Weight 142.22
Chemical Name or Material Diisobutylaluminum hydride
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