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Nickel(II) chloride hexahydrate, 98%
Beskrivelse
Nickel(II) chloride is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is used to prepare a wide array of complexes since water ligands can be easily replaced by amines, thioether, ammonia, and thiolates. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Nickel(II) chloride is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is used to prepare a wide array of complexes since water ligands can be easily replaced by amines, thioether, ammonia, and thiolates. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
Notes
Store away from incompatible substances such as peroxides, strong acids and potassium.
Tekniske data
Tekniske data
| Melting Point | 140°C (in 2H2O) |
| pH | 4.9 |
| Quantity | 250 g |
| Linear Formula | NiCl2·6H2O |
| UN Number | UN3288 |
| Merck Index | 14,6505 |
| Solubility Information | Freely soluble in water. Soluble in ethylene glycol,ethanol,and ammonium hydroxide. |
| Formula Weight | 237.71 (129.60 Anhydrous) |
| Percent Purity | 98% |
| Odor | Odorless |
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Sikkerhed og håndtering
- Nickel(II) chloride hexahydrate
- Danger
- Acute toxicity Category 3
- LONG-TERM AQUATIC HAZARD Chronic 1
- ACUTE AQUATIC Acute 1
- Carcinogenicity Category 1A
- Germ cell mutagenicity Category 2
- Reproductive toxicity Category 1B
- Respiratory sensitiser Category 1
- Skin corrosion/irritation Category 2
- Skin sensitiser Category 1
- Specific target organ toxicity Category 1
- H301-Toxic if swallowed.
- H315-Causes skin irritation.
- H317-May cause an allergic skin reaction.
- H331-Toxic if inhaled.
- H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled.
- H341-Suspected of causing genetic defects.
- H350i-May cause cancer by inhalation.
- H360D-May damage the unborn child.
- H372-Causes damage to organs.
- H400-Very toxic to aquatic life.
- H410-Very toxic to aquatic life with long lasting effects.
- P260-Do not breathe dust/fume/gas/mist/vapours/spray.
- P273-Avoid release to the environment.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P308+P313-IF exposed or concerned: Get medical advice/attention.
- MIXTURE LIST-Contains : Nickel(II) chloridehexahydrate, Nickel(II) chloride
RUO – Research Use Only
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