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  7. Sodium bis(trimethylsilyl)amide, 1M soln. in THF, Thermo Scientific Chemicals

Sodium bis(trimethylsilyl)amide, 1M soln. in THF, Thermo Scientific Chemicals

Catalog Number 11352706
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Quantity:
100 mL
500 mL
1070-89-9
C6H18NNaSi2
183.377
MFCD00009835
WRIKHQLVHPKCJU-UHFFFAOYSA-N
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
2724254
sodium;bis(trimethylsilyl)azanide
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
1070-89-9
C6H18NNaSi2
183.377
MFCD00009835
WRIKHQLVHPKCJU-UHFFFAOYSA-N
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
2724254
sodium;bis(trimethylsilyl)azanide
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]

Description

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(trimethylsilyl)amide is useful for the generation of carbenes, the amination of sulfonamides, and for the preparation of lanthanide complexes. It is significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis. It is used to deprotonate ketones and esters to generate enolate derivatives, phosphonium salts, generating Wittig reagents.

Solubility
Soluble in benzene, toluene and ether. Reacts with water.

Notes
Moisture Sensitive. Incompatible materials are Oxidizing agents, Oxygen. Store away from water and oxidizing agents.
TRUSTED_SUSTAINABILITY
Quantity 500 mL
UN Number UN2924
Beilstein 3629917
Flash Point −17°C (1°F)
Solubility Information Soluble in benzene,toluene and ether. Reacts with water.
Formula Weight 183.38
Concentration or Composition (by Analyte or Components) 1M soln. in THF
Sensitivity Moisture sensitive; May form a precipitate
Density 0.904
Chemical Name or Material Sodium bis(trimethylsilyl)amide

RUO – Research Use Only

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