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tert-Butyldichlorophosphine, 98%

Product Code. 11337129
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11317129 1 g 1g
11327129 10 g 10g
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Product Code. 11337129

Brand: Thermo Scientific Alfa Aesar H27360.18

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Description

CAS: 25979-07-1 | C4H9Cl2P | 158.99 g/mol

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.

Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 25979-07-1
Molecular Formula C4H9Cl2P
Molecular Weight (g/mol) 158.99
MDL Number MFCD00013615
InChI Key NMJASRUOIRRDSX-UHFFFAOYSA-N
Synonym tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride
PubChem CID 117690
IUPAC Name tert-butyl(dichloro)phosphane
SMILES CC(C)(C)P(Cl)Cl

Specifications

Melting Point 44°C to 49°C
Linear Formula (CH3)3CPCl2
Quantity 50 g
UN Number UN3261
Sensitivity Air and moisture sensitive
Solubility Information Reacts with water. Soluble in n-Pentane,n-Hexane,Ether,Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Formula Weight 159
Percent Purity 98%
Chemical Name or Material tert-Butyldichlorophosphine

RUO – Research Use Only

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