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  7. Triethyl phosphonoacetate, 98+%

Triethyl phosphonoacetate, 98+%

Product Code. 11438086
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Product Code. 11438086 Supplier Thermo Scientific Alfa Aesar Supplier No. A14120.22
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Description

CAS: 867-13-0 | C8H17O5P | 224.193 g/mol

Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.

Solubility
Slightly miscible with water.

Notes
Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 867-13-0
Molecular Formula C8H17O5P
Molecular Weight (g/mol) 224.193
MDL Number MFCD00009177
InChI Key GGUBFICZYGKNTD-UHFFFAOYSA-N
Synonym triethyl phosphonoacetate, ethyl 2-diethoxyphosphoryl acetate, ethyl diethoxyphosphoryl acetate, ethyl diethylphosphono acetate, triethyl phosphonoethanoate, diethyl carboethoxymethylphosphonate, diethyl ethoxycarbonylmethanephosphonate, diethylphosphonoacetic acid ethyl ester, diethyl carbethoxymethylphosphonate
PubChem CID 13345
IUPAC Name ethyl 2-diethoxyphosphorylacetate
SMILES CCOC(=O)CP(=O)(OCC)OCC

Spécification

Melting Point -24°C
Density 1.125
Boiling Point 260°C to 262°C
Flash Point 165°C (329°F)
Refractive Index 1.431
Quantity 100 g
Beilstein 1343714
Solubility Information Slightly miscible with water.
Formula Weight 224.19
Percent Purity ≥98%
Chemical Name or Material Triethyl phosphonoacetate
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Sécurité et traitement

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Identifiant produit
  • Triethyl phosphonoacetate
 Mention d'avertissement
  • Danger
 Catégorie de danger
  • Serious eye damage/eye irritation Category 1
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Mention de danger
  • H315-Causes skin irritation.
  • H318-Causes serious eye damage.
  • H335-May cause respiratory irritation.
 Conseils de prudence
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Informations supplémentaires
  • MIXTURE LIST-Contain: Triethyl phosphonoacetate
FDS

RUO – Research Use Only

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