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  6. Triphenylcarbenium hexafluorophosphate, 98%

Triphenylcarbenium hexafluorophosphate, 98%

Product Code. 11332036
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Quantity:
10 g
50 g
Unit Size:
10g
50g
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Product Code. 11332036

Brand: Thermo Scientific Alfa Aesar L03140.09

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Description

CAS: 437-17-2 | C19H15F6P | 388.29 g/mol

Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of push-pull tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of ″push-pull″ tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

Solubility
Soluble in water. (27 g/L) at 25°C.

Notes
Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 437-17-2
Molecular Formula C19H15F6P
Molecular Weight (g/mol) 388.29
MDL Number MFCD00013121
InChI Key IBTFOFOFRZKIJU-UHFFFAOYSA-N
Synonym triphenylcarbenium hexafluorophosphate, trityl hexafluorophosphate, tritylium hexafluorophosphate, triphenylmethyl hexafluorophosphate, triphenylcarbonium hexafluorophosphate, tritylium, hexafluorophosphate 1-, triphenyl-methyliuhexafluorophosphate 1-, ph3cpf6, methylium, triphenyl-, hexafluorophosphate 1-, methylium, hexafluorophosphate 1-
PubChem CID 2723954
IUPAC Name diphenylmethylbenzene;hexafluorophosphate
SMILES F[P-](F)(F)(F)(F)F.C1=CC=C(C=C1)[C+](C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∽160°C (decomposition)
Linear Formula (C6H5)3CPF6
Quantity 10 g
UN Number UN3261
Beilstein 4344297
Sensitivity Moisture sensitive
Solubility Information Soluble in water. (27g/L) at 25°C.
Formula Weight 388.29
Percent Purity 98%
Chemical Name or Material Triphenylcarbenium hexafluorophosphate

RUO – Research Use Only

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