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  8. (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+%

(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+%

Product Code. 11306669
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Product Code. Quantity unitSize
11306669 5 g 5g
11316669 25 g 25g
11326669 100 g 100g
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Product Code. 11306669

Brand: Thermo Scientific Alfa Aesar H26226.06

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Description

CAS: 98327-87-8 | C44H32P2 | 622.69 g/mol

(±)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl plays an essential role in the organic synthesis of enantioselective transformations catalyzed by the complexes of ruthenium, rhodium and palladium. It is also employed in palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. It is used with Cu(II) to catalyze the addition of arylsulfonamides to styrenes and olefins.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(^+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl plays an essential role in the organic synthesis of enantioselective transformations catalyzed by the complexes of ruthenium, rhodium and palladium. It is also employed in palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. It is used with Cu(II) to catalyze the addition of arylsulfonamides to styrenes and olefins.

Solubility
Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Notes
Air sensitive. Keep container tightly closed in a dry and well-ventilated place.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 98327-87-8
Molecular Formula C44H32P2
Molecular Weight (g/mol) 622.69
MDL Number MFCD00010805
InChI Key MUALRAIOVNYAIW-UHFFFAOYSA-N
Synonym binap, r-+-2,2'-bis diphenylphosphino-1,1'-binaphthyl, 2,2'-bis diphenylphosphino-1,1'-binaphthyl, s-binap, s---binap, s---2,2'-bis diphenylphosphino-1,1'-binaphthyl, r-+-binap, r-binap, rac-binap, 2,2'-bis diphenylphosphino-1,1'-binaphthalene
PubChem CID 634876
IUPAC Name [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
SMILES C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=C(C2=CC=CC=C2C=C1)C1=C(C=CC2=CC=CC=C12)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 281°C to 285°C
Quantity 5 g
Beilstein 5321443
Merck Index 14,1223
Solubility Information Soluble in tetrahydrofuran,benzene and dichloromethane. Slightly soluble in ether,methanol and ethanol. Insoluble in water.
Formula Weight 622.69
Percent Purity 98%
Chemical Name or Material (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

Safety and Handling

compliance-icons
Product Identifier
  • (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
 Signal Word
  • Warning
 Hazard Category
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Supplemental information
  • MIXTURE LIST-Contains : (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
SDS

RUO – Research Use Only

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