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Benzhydryl bromide, 90+%

Product Code. 11351547
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Product Code. Quantity unitSize
11351547 25 g 25g
11361547 100 g 100g
11371547 500 g 500g
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Product Code. 11351547

Brand: Thermo Scientific Alfa Aesar L02211.14

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Description

CAS: 776-74-9 | C13H11Br | 247.135 g/mol

Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

Solubility
Insoluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to moisture. Protect from humidity and water. Store under dry inert gas.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 776-74-9
Molecular Formula C13H11Br
Molecular Weight (g/mol) 247.135
MDL Number MFCD00000134
InChI Key OQROAIRCEOBYJA-UHFFFAOYSA-N
Synonym bromodiphenylmethane, benzhydryl bromide, diphenylmethyl bromide, diphenylbromomethane, alpha-bromodiphenylmethane, bromo phenyl methyl benzene, benzene, 1,1'-bromomethylene bis, methane, bromodiphenyl, bromomethylene dibenzene, bromodiphenyl methane
PubChem CID 236603
IUPAC Name [bromo(phenyl)methyl]benzene
SMILES C1=CC=C(C=C1)C(C2=CC=CC=C2)Br

Specifications

Melting Point 36°C to 41°C
Boiling Point 183°C to 185°C (20 mmHg)
Flash Point >110°C (230°F)
Odor Pungent
Quantity 25 g
UN Number UN1770
Beilstein 638544
Sensitivity Moisture sensitive
Solubility Information Insoluble in water.
Formula Weight 247.14
Percent Purity ≥90%
Chemical Name or Material Benzhydryl bromide
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